A transition-metal-free Heck-type reaction between alkenes and alkyl iodides enabled by light in water.
نویسندگان
چکیده
A transition-metal-free coupling protocol between various alkenes and non-activated alkyl iodides has been developed by using photoenergy in water for the first time. Under UV irradiation and basic aqueous conditions, various alkenes efficiently couple with a wide range of non-activated alkyl iodides. A tentative mechanism, which involves an atom transfer radical addition process, for the coupling is proposed.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 13 22 شماره
صفحات -
تاریخ انتشار 2015